Ann M Ebner, 65Mayfield Village, OH

5053577, Oct 1, 1991

May 25, 1990

7/528859

Raymond G. Teller - Aurora OH
Ann M. Ebner - Lyndhurst OH
Christopher Bodolus - Cleveland Hts. OH
Victor R. Gupta - Cleveland Hts. OH

The Standard Oil Company - Cleveland OH

C07C 200

585500

High-temperature, attrition resistant, oxidation catalysts are disclosed. These catalysts are represented by the formula A. sub. u MO. sub. w [(DO. sub. x)(EO. sub. y). sub. a ]. sub. z wherein A is an alkali or alkaline earth metal; M is V, Cr, Mo, Mn, Fe, Co, Ni, Cu or a mixture of two or more thereof; D is Zr, Ti, Hf, Ce, Th, Pr, Nb, Ta, W, Re or a mixture of two or more thereof; E is Ca, Mg, Sr, Ba, Y, La, Yb, Sm, Gd, Nd, Sc, V, Bi, Ce, Pr, Eu, Tb, Dy, Ho, Er, Tm, Lu or a mixture of two or more thereof; a is a number in the range of zero up to about 0. 2; u is a number in the range of zero to about 1; w is the number of oxygens needed to fulfill the valence requirement of A and M; x is the number of oxygens needed to fulfill the valence requirements of D; y is the number of oxygens needed to fulfill the valence requirements of E; and z is a number in the range of about 10 to about 100. The invention further provides for the use of such catalysts in processes involving the combustion of organic materials (e. g. , carbonaceous fuels, organic waste materials, etc.

4968661, Nov 6, 1990

Nov 8, 1989

7/433678

Raymond G. Teller - Aurora OH
Ann M. Ebner - Lyndhurst OH
Christopher Bodolus - Cleveland Heights OH
Victor R. Gupta - Cleveland Heights OH

The Standard Oil Company - Cleveland OH

B01J 2106
B01J 2302
B01J 2310

502304

High-temperature, attrition resistant, oxidation catalysts are disclosed. These catalysts are represented by the formula A. sub. u MO. sub. w [(DO. sub. x)(EO. sub. y). sub. a ]. sub. z wherein A is an alkali or alkaline earth metal; M is V, Cr, Mo, Mn, Fe, Co, Ni, Cu or a mixture of two or more thereof; D is Zr, Ti, Hf, Ce, Th, Pr, Nb, Ta, W, Re or a mixture of two or more thereof; E is Ca, Mg, Sr, Ba, Y, La, Yb, Sm, Gd, Nd, Sc, V, Bi, Ce, Pr, Eu, Tb, Dy, Ho Er, Tm, Lu or a mixture of two or more thereof; a is a number in the range of zero up to about 0. 2; u is a number in the range of zero to about 1; w is the number of oxygens needed to fulfill the valence requirement of A and M; x is the number of oxygens needed to fulfill the valence requirements of D; y is the number of oxygens needed to fulfill the valence requirements of E; and z is a number in the range of about 10 to about 100. This invention further provides for the use of such catalysts in processes involving the combustion of organic materials (e. g. , carbonaceous fuels, organic waste materials, etc.

4836117, Jun 6, 1989

Jan 15, 1988

7/144800

Raymond G. Teller - Aurora OH
Ann M. Ebner - Lyndhurst OH
Christopher Bodolus - Cleveland Hts. OH
Victor R. Gupta - Cleveland Hts. OH

The Standard Oil Company - Cleveland OH

F23B 700

110342

High-temperature, attrition resistant, oxidation catalysts are disclosed. These catalysts are represented by the formula AMO. sub. w [(DO. sub. x)(EO. sub. y)a]z wherein A is an alkali or alkaline earth metal; M is V, Cr, Mo, Mn, Fe, Co, Ni, Cu or a mixture of two or more thereof; D is Zr, Ti, Hf, Ce, Th, Pr, Nb, Ta, W, Re or a mixture of two or more thereof; E is Ca, Mg, Sr, Ba, Y, La, Yb, Sm, Gd, Nd, Sc, V, Bi, Ce, Pr, Eu, Tb, Dy, Ho, Er, Tm, Lu or a mixture of two or more thereof; a is a number in the range of zero up to about 0. 2; w is the number of oxygens needed to fulfill the valence requirement of AM; x is the number of oxygens needed to fulfill the valence requirements of D; y is the number of oxygens needed to fulfill the valence requirements of E; and z is a number in the range of about 10 to about 100. The invention further provides for the use of such catalysts in processes involving the combustion of organic materials (e. g. , carbonaceous fuels, organic waste materials, etc.

5198580, Mar 30, 1993

Nov 18, 1991

7/793910

Joseph P. Bartek - Highland Heights OH
Ann M. Ebner - Lyndhurst OH
James R. Brazdil - Mayfield Village OH

The Standard Oil Company - Cleveland OH

C07C 5116

562542

Disclosed is a process for the partial oxidation of propane to yield acrylic acid, propylene, acrolein and acetic acid by contacting propane in admixture with a molecular oxygen-containing gas in a reaction zone with an oxidic solid catalyst that 1) contains the components and proportions represented by the empirical formula Bi. sub. b Mo. sub. c V. sub. v A. sub. a D. sub. d E. sub. e O. sub. x wherein A is one or more of K, Na, Li, Cs and Tl, D is one or more of Fe, Ni, Co, Zn, Ce and La, E is one or more of W, Nb, Sb, Sn, P, Cu, Pb, B, Mg, Ca and Sr, a, d and e are each zero-10 b is 0. 1-10 c is 0. 1-20 v is 0. 1-10 c:b is from 2:1 to 30:1 v:b is from 1. 5:1 to 8:1 and 2) is made by performing a bismuth molybdate containing composition having at least 0. 67 atoms of Mo per atom of Bi, before combining with any vanadium compound.