Inventors:
Edward D. Babich - Chappaqua NY
Jeffrey D. Gelorme - Plainville CT
Michael Hatzakis - Chappaqua NY
Jane M. Shaw - Ridgefield CT
Kevin J. Stewart - Lake Peekskill NY
David F. Witman - Pleasantville NY
Assignee:
International Business Machines Corporation - Armonk NY
International Classification:
G03F 7075
G03F 726
Abstract:
An ultraviolet light sensitive photoinitiator composition that includes at least one anthracene derivative represented by the formula: ##STR1## wherein X is CH. dbd. CH. sub. 2 or --(--CH. sub. 2 --)--. sub. n O--(--R) with R being H or ##STR2## wherein each R. sup. I, R. sup. II and R. sup. III individually is selected from the group of alkyl, alkenyl, aryl, ##STR3## wherein each R. sup. IV, R. sup. V and R. sup. VI individually is selected from the group of alkyl, alkenyl and aryl; wherein m is an integer of 0 to 4, p is an integer of 0 to 4; and is n being 1 to 2; and onium salt; and an organic solvent. The composition is used for cationic polymerization of cationic polymerizable materials including in the formation of a pattern of a photoresist. Also certain novel epoxy-functionalized organosilicons are provided that are sensitive to radiation including E-beam radiation and exhibit resistance to oxygen reactive ion etching.