Inventors:
Shruti Singhal - Villanova PA
Rainer Hoefer - Neuss, DE
John E. Nowicki - Hatfield PA
George Roth - Homewood IL
Darmesh Chovatia - Bensalem PA
Shailesh Shah - Dresher PA
Assignee:
Cognis Corporation - Gulph Mills PA
International Classification:
C08J22010
US Classification:
52631844, 526 68, 5263171, 526320, 526318
Abstract:
The invention relates to a process for producing a polymer or copolymer from monomer material comprising an acrylate, methacrylate, or mixture of such monomers, which comprises the steps of: (a) charging into a continuous tube reactor a feedstock comprising said monomer material and a polymerization initiator; (b) maintaining a flow rate of said material through the reactor at a reaction temperature in the reactor and under pressure sufficient to provide a residence time of the feedstock in the reactor during which polymerization will occur, to form a resin product in the reactor, and said resulting resin product comprising unreacted monomer, and (c) devolatilizing said resin product exiting the reactor to remove unreacted monomers, to provide a substantially monomer-free resin product. Further, the invention relates to resin product made by the process. In particular, the invention relates to resin that has a weight average molecular weight of 10,000 or less, and a glass transition temperature of less than 0Â C.