Joseph S Arvay, 5810673 Melody Dr, Denver, CO 80234

4655437, Apr 7, 1987

Feb 3, 1986

6/825255

Leonard Fritz - Romulus MI
Richard R. Osterberg - Canton MI
Richard B. Wolanski - Dexter MI
Joseph E. Arvay - Trenton MI

Huron Valley Steel Corp. - Belleville MI
Fritz Enterprises, Inc. - Taylor MI

C22B 400

266197

A method and apparatus for simultaneously separating volatile metals, including zinc and lead, and non-volatile metals, including copper, from mixtures of metallic and metallic oxide. Finely pulverized metal containing material, is continuously fed into the reactor chamber along with pulverized carbonaceous material, such as coke, and also oxygen or air. The reactor chamber is intensely heated by a transferred arc plasma generator to provide sufficient heat energy which together with the reducing gases cause a reducing reaction and melt the non-volatile copper and other metals which form a puddle upon the floor of the reaction chamber and to form a layer of slag covering the puddle, and simultaneously to vaporize the volatile zinc, lead and the like metals.

4606760, Aug 19, 1986

May 3, 1985

6/729994

Leonard Fritz - Romulus MI
Richard R. Osterberg - Canton MI
Richard B. Wolanski - Dexter MI
Joseph E. Arvay - Trenton MI

Huron Valley Steel Corp. - Belleville MI
Fritz Enterprises, Inc. - Taylor MI

C22B 400

75 1019

A method and apparatus for simultaneously separating volatile metals, including zinc and lead, and non-volatile metals, including copper, from mixtures of metallic and metallic oxide and the like materials, includes a reactor having a lower, reactor, chamber, an upper, reflux, chamber and a vertically arranged, hollow shaft interconnecting the two chambers. The shaft is substantially filled with a mixture of pieces of metallic material, having minimal oxide content, and carbonaceous material, such as coke. The reactor chamber is intensely heated by a transferred arc plasma generator to provide sufficient heat energy which together with reducing gases cause a reducing reaction and melt the non-volatile copper and other metals which form a puddle upon the floor of the reaction chamber and to form a layer of slag covering the puddle, and simultaneously to vaporize the volatile zinc, lead and the like metals. The reflux chamber is maintained at a temperature and vapor pressure suitable to condense the lead vapor, but insufficient to condense zinc vapor. Thus, condensed lead gravity flows back down the shaft through the filling for deposit in the puddle.