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Sebastian Eraso Reyes
Sebastian Reyes
Sebastian Reyes
Sebastian Orellana Reyes
Sebastian Reyes
Location:
United States
Sebastian ReyesBarrigada, GU
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Hayward, CA
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Publications & IP owners
Us Patents
Process And Catalyst For Oxidation Of Hydrocarbons
US Patent:
7868201, Jan 11, 2011
Filed:
Jul 1, 2005
Appl. No.:
11/173594
Inventors:
Bjorn Moden - Berkeley CA, US
Jihad Dakka - Whitehouse Station NJ, US
Jose Santiesteban - Baton Rouge LA, US
Sebastian C. Reyes - Branchburg NJ, US
Enrique Iglesia - Moraga CA, US
Jihad Dakka - Whitehouse Station NJ, US
Jose Santiesteban - Baton Rouge LA, US
Sebastian C. Reyes - Branchburg NJ, US
Enrique Iglesia - Moraga CA, US
Assignee:
ExxonMobil Research and Engineering Company - Annandale NJ
International Classification:
C07C 51/00
C07C 45/00
C07C 27/10
B01J 29/06
B01J 29/068
B01J 29/072
C07C 45/00
C07C 27/10
B01J 29/06
B01J 29/068
B01J 29/072
US Classification:
562412, 562417, 562504, 562523, 562527, 562531, 562538, 562542, 562549, 568320, 568357, 568375, 568376, 5683988, 568399, 568431, 5684699, 568475, 568815, 568821, 568836, 568910, 5689105, 502 64, 502 66, 502 71
Abstract:
A process for the oxidation of hydrocarbons comprises contacting the hydrocarbon with an oxygen-containing gas in the presence of a catalyst comprising a microporous solid support, preferably a zeolite, having from 8- to 12-ring open windows and comprising non-framework metal cations selected from manganese, iron, cobalt, vanadium, chromium, copper, nickel, and ruthenium, and mixtures thereof, providing that the oxygen-containing gas does not contain significant amounts of added hydrogen. The catalyst is novel and forms part of the invention. The process may be used for oxidation of alkanes, cycloalkanes, benzene and alkylbenzenes, and is suitable for use in regioselective terminal oxidation of straight chain alkanes and for selective oxidation/separation of p-dialkylbenzenes from an alkylbenzene mixture, for example, p-xylene from an isomeric mixture of xylenes.
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