Inventors:
Srinivas Gandikota - Santa Clara CA, US
Xinliang Lu - Fremont CA, US
Shih Chung Chen - Cupertino CA, US
Wei Tang - Santa Clara CA, US
Jing Zhou - Milpitas CA, US
Seshadri Ganguli - Sunnyvale CA, US
David Thompson - San Jose CA, US
Jeffrey W. Anthis - San Jose CA, US
Atif Noori - Saratoga CA, US
Faruk Gungor - San Jose CA, US
Dien-Yeh Wu - San Jose CA, US
Mei Chang - Saratoga CA, US
Xinyu Fu - Fremont CA, US
Yu Lei - Foster City CA, US
International Classification:
C23C 18/00
Abstract:
Provided are methods of depositing films comprising alloys of aluminum, which may be suitable as N-metal films. Certain methods comprise exposing a substrate surface to a metal halide precursor comprising a metal halide selected from TiCl, TaCland HfClto provide a metal halide at the substrate surface; purging metal halide; exposing the substrate surface to an alkyl aluminum precursor comprising one or more of dimethyaluminum hydride, diethylhydridoaluminum, methyldihydroaluminum, and an alkyl aluminum hydrides of the formula [(CxHy)AlH], wherein x has a value of 1 to 3, y has a value of 2x+2, a has a value of 1 to 2, and n has a value of 1 to 4; and exposing the substrate surface to an alane-containing precursor comprising one or more of dimethylethylamine alane, methylpyrrolidinealane, di(methylpyrolidine)alane, and trimethyl amine alane borane. Other methods comprise exposing a substrate surface to a metal precursor and trimethyl amine alane borane.